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Name: bpc 157 synthetic BPC-157: Tendon Repair and More BPC-157 Peptide Therapy | Doctors
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Endocrine Journal , 59(7), 529538

In most cases yes, but there are exceptions such as levodopa for Parkinsons disease and certain antibiotics

The lifetime of the MLCT state is inversely related to the size of the alkyl ligand: 1 ns (methyl), 48 ps (ethyl), 32 ps (n-propyl), and 14 ps (adenosyl, if the MLCT state is present).Excitation at 400 nm opens a pathway for direct photohomolysis of the carbon-cobalt bond in methyl-, ethyl-, and n-propylcobalamin