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GSK3 directly regulates at least forty known downstream substrates that participate in a diverse range of cellular processes [172]

Quercetin, luteolin, and apigenin can prevent NLRP3 inflammasome assembly, activate caspase-1, and cleave Gasdermin D (GSDMD) through reactive oxygen species (ROS) scavenging or Nrf2/HO-1 activation, thereby decreasing IL-1 secretion, inhibiting macrophage pyroptosis, and suppressing macrophage-driven inflammation (9496)

Unfortunately, it seems to be limited , or to quote a great article from the Journal of Cosmetic Dermatology "topically applied ascorbyl phosphate salts are, at very best, poorly absorbed in comparison with AA"

Besides direct microbial killing, ROS are also involved in immune responses and emerging as central signaling molecules in the inflammatory response (32)